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Original scientific paper

INVESTIGATION OF INHIBITORY EFFECT OF THE RASPBERRY FRUIT EXTRACT (Rubus idaeus L.) ON CORROSION OF COPPER IN 3% NaCl SOLUTION

By
Dejana Kasapović ,
Dejana Kasapović
Contact Dejana Kasapović

Faculty of Engineering and Natural Sciences, University of Zenica , Zenica , Bosnia and Herzegovina

Fehim Korać ,
Fehim Korać

Faculty of Sciences, University of Sarajevo , Sarajevo , Bosnia and Herzegovina

Farzet Bikić
Farzet Bikić

Faculty of Engineering and Natural Sciences, University of Zenica , Zenica , Bosnia and Herzegovina

Abstract

The paper presents an examination of the possibility of applying raspberry fruit extract (Rubus idaeus L.) as a green inhibitor of general corrosion of copper in 3% NaCl. Raspberry fruits (Rubus idaeus L.) sort Polka was collected from the Starposle near Kakanj, Bosnia and Herzegovina. Raspberry fruit extracts in ethanol were obtained by the Soxhlet extraction and the ultrasonic method. By UV/VIS spectrophotometry analysis, a significant content of polyphenols was found in the raspberry fruit extracts. Due to the great importance of gallic acid, the concentration of gallic acid was also determined using liquid chromatography. Corrosion testing of copper by the DC techniques was performed on a measuring device consisting of an electrochemical cell and a potentiostat/galvanostat, and electrochemical impedance spectroscopy measurements were performed using a potentiostat/galvanostat. Results obtained by the DC technique (by the method of Tafel extrapolation) prove that the corrosion rate decreases in the presence of the raspberry fruit extract. Tests performed by the method of electrochemical impedance spectroscopy prove that the tested extracts slow down the kinetics of the corrosion process, which is visible through the increase in resistance. The results of the conducted tests prove that in an aggressive medium, such as a 3% NaCl solution, Polka raspberry fruit extract can be used as an inhibitor of copper’s corrosion.

References

Anđelković, A. S. M. (2016). Ekstrakcija, karakterizacija, biološka aktivnost i potencijalna primena fenolnih jedinjenja iz plodova i lišća biljnih vrsta familija Rosaceae, Cornaceae i Grossulariaceae.
Badhani, B., Sharma, N., & Kakkar, R. (2015). Gallic acid: a versatile antioxidant with promising therapeutic and industrial applications. RSC Advances, 35, 27540–27557.
Barcia, O. E., Mattos, O. R., Pebere, N., & Tribollet, B. (1993). Mass‐Transport Study for the Electrodissolution of Copper in 1M Hydrochloric Acid Solution by Impedance. Journal of The Electrochemical Society, 140, 2825.
Bikić, F. (2017). Korozija i zaštita, Univerzitet u Zenici, Fakultet za metalurgiju i materijale.
Čurković, H. O., Stupnišek-Lisac, E., & Takenouti, H. (2010). The influence of pH value on the efficiency of imidazole-based corrosion inhibitors of copper. Corrosion Science, 52, 398–405.
Deslouis, C., Tribollet, B., Mengoli, G., & Musiani, M. M. (1988). Electrochemical behaviour of copper in neutral aerated chloride solution. I. Steady-State Investigation, Journal of Applied Electrochemistry, 18, 374–383.
El-Tantawy, M. I., Gadow, H. S., Rashed, I. G., & El-Aziz, S. F. A. (2022). Inhibition of Copper Corrosion by Rice Straw Extract in 2M Solution of Nitric Acid. Biointerface Research in Applied Chemistry, 12, 83–104.
G5-94, A. S. T. M. (n.d.). Standard Reference Test Method for Making Potentiostatic and Potentiodynamic Anodic Polarization Measurements.
Grudić, V., Bošković, I., & Gezović, A. (2018). Inhibition of Copper Corrosion in NaCl Solution by Propolis Extract. Chemical and Biochemical Engineering Quarterly, 32, 299–305.
Kear, G., Barker, B. D., & Walsh, F. C. (2004). Electrochemical corrosion of unalloyed copper in chloride media–a critical review. Corrosion Science, 46, 109–135.
Khalid, A. R., & Shengtao, Z. (2019). Alchemilla Vulgaris Extract as Green Inhibitor of Copper Corrosion in Hydrochloric Acid. International Journal of Electrochemical Science, 14, 10657–10669.
Nami, S. Y., & El-Aziz, S. F. A. (2019). Calotropis Procera Extract as Corrosion Inhibitor for Copper in Nitric Acidic Environment. International Journal of Electrochemical Science, 14, 6902–6919.
Otmačić, H., & Stupnišek-Lisac, E. (2003). Copper corrosion inhibitors in near neutral media. Electrochimica Acta, 48, 985–991.
Radošević, J. (2012). Ekološki prihvatljivi inhibitori korozije legura aluminija i bakra. Zaštita Materijala, 53, 313–323.
Revie, R. W. (2000). Anti-Corrosion Methods and Materials, Uhlig’s Corrosion Handbook (Vol. 47, Issue 4).
Vinčić, M. (2017). Antioksidativna, antiproliferativna i antimikrobna aktivnost odabranih ekstrakata tropova bobičastog voća.

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